Alice (Closer): Notice how she handled being in love. When Dan told started talking about how it unsettled him that she was with Larry, she flatly said "I don't think I love anymore". NFs handle love with a lot more reverence than that. Also, Dan is a rare "asshole ENFP" character (I've never seen ENFP villain in another movie). He provoked the feeling of love in people as a tool for own narcissistic desires.
Eternal Sunshine: It's easy to see Clementine's ESFP-ishness when she had her temper tantrums. She was a lot more upfront confrontational than an ENFP would be. NFs pride themselves on the apparent diplomatic competency. Joel is a classic case of an insecure ISFJ - a boiling pot of inhibited feelings. Whenever ISFJs inhibit their feelings they become very passive aggressive. Like Joel he handled himself when he noticed that his car was damaged. He put a sarcastic note "Thank you" on a car next to his. He didn't do it as a snark, he did in way that looked like it was the only option available to him to deal with that situation (you could tell because he was clearly agitated by the incident). Also, Joel is obsessed about the past. Often to an SJ, the present and the future can never match the nostalgia of the past. I don't know if you met an ISFJ with an ex before, but the ISFJs have a habit of mentally rewriting the history of their failed personal relationships to make it look that it was in fact something wonderful that was lost for some tragic reason. In their mind it is always a lot better than it really was.
Tony (scarface): I actually had a dispute about him with another person, so I'll copy and paste most of the stuff from that argument:
Tony Montana wasn't really a planner or a long term strategist (like an NT). Tony didn't care much for politics, he carelessly made a lot of enemies because he refused to follow any sort of order or hierarchy for no good reason aside from the fact that he didn't like being told what to do. Although ENTJs don't shy away from confrontations, there is usually a reason for a confrontation (because ENTJs view power as more encompassing than mere physical domination, and therefore pay a lot more emphasis to politics than ESTPs). For Tony Montana, going against the grain was a way of life - his personality was that of a "Rebel" which in the movies is mostly associated with ESTPs. ESTP is a typical rebel who causes headache to authority and believes that there is no argument under the sun that cannot be solved with a good old fashioned fist fight. This character borders on being a troglodyte, no matter what his profession, be it an outlaw like Tony Montana in Scarface or doctor like Larry in Closer, male ESTP is the typical jerk who women pretend to despise, yet always fall for. Kind of like what happened to Tony and Elvira. The "rebel" character tends to be street smart and can handle his own affairs pretty well, but his organizational skills tend to be lacking. He is capable of starting rebellion, but when it comes to running complex organizations, his lack of planning gets the better of him and the ESTP finds himself replaced by somebody more competent, usually an INTJ (Mark Anthony replaced with Octavian, Sonny Corleone replaced with Michael Corleone). That theme runs through Scarface as well. Tony recklessly crosses Alejandro Sosa (a likely INTJ), and in the end gets destroyed. The reason I say recklessly is because Tony had no plan on crossing Sosa until one of his own personal rules was about to be violated (women and children were about to get killed). Male xSTP rules tend to revolve around "masculine honor" - i.e. "I don't kick a man when he's down", and "I don't kill children" etc).
Tuco (from Good/Bad/Ugly): I actually have to rewatch the movie to make a good argument for this one.